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Adachi, Nozomu*; Ueno, Haruki*; Onoe, Katsuhiko*; Morooka, Satoshi; Todaka, Yoshikazu*
ISIJ International, 61(8), p.2320 - 2322, 2021/08
Times Cited Count:3 Percentile:25.78(Metallurgy & Metallurgical Engineering)Sakaba, Nariaki; Ohashi, Hirofumi; Takeda, Tetsuaki
Journal of Nuclear Materials, 353(1-2), p.42 - 51, 2006/07
Times Cited Count:10 Percentile:53.38(Materials Science, Multidisciplinary)The permeation of hydrogen isotopes through the Hastelloy XR high-temperature alloy adopted for the heat transfer pipes of the intermediate heat exchanger in the HTTR, is one of the concerns in the hydrogen production system, which will be connected to the HTTR in the near future. The hydrogen permeation between the primary and secondary coolant through the Hastelloy XR was evaluated using the actual hydrogen concentration observed during the initial 950C operation of the HTTR. The hydrogen permeability of the Hastelloy XR was estimated conservatively high as follows. The activation energy E and pre-exponential factor F of the permeability of hydrogen were E = 65.8 kJ/mol and F = 7.810m(STP)/(msPa), respectively, in the temperature range from 707K to 900K.
Kulsartov, T. V.*; Hayashi, Kimio; Nakamichi, Masaru*; Afanasyev, S. E.*; Shestakov, V. P.*; Chikhray, Y. V.*; Kenzhin, E. A.*; Kolbaenkov, A. N.*
Fusion Engineering and Design, 81(1-7), p.701 - 705, 2006/02
Times Cited Count:41 Percentile:92.46(Nuclear Science & Technology)no abstracts in English
Kawamura, Yoshinori; Iwai, Yasunori; Nakamura, Hirofumi; Hayashi, Takumi; Yamanishi, Toshihiko; Nishi, Masataka
Fusion Science and Technology, 48(1), p.654 - 657, 2005/07
Times Cited Count:3 Percentile:24.22(Nuclear Science & Technology)Adding some amount of hydrogen to the helium sweep gas is effective for tritium extraction from blanket, but it causes permeation of tritium to a cooling system. In the design study of a demonstration reactor in JAERI, tritium leakage has been estimated to be about 20% of bred tritium under typical sweep gas conditions. If these tritiums are recovered under the ITER-WDS condition, tritium leakage limitation has to be less than 0.3% of typical case. Water vapor addition to the sweep gas is effective not only for blanket tritium extraction but also for permeation prevention. The reaction rate of isotope exchange is larger than the case of H, and the equilibrium constant is also expected to be about 1.0. When the H/T ratio is 100, tritium inventory of breeder material is larger than the case of H addition. However it is not so large. In case of HO sweep, separation of tritiated water from helium seems to be easyer, but the process that changes HTO to HT is necessary.
Ohashi, Hirofumi; Nishihara, Tetsuo; Takeda, Tetsuaki; Inagaki, Yoshiyuki
Proceedings of 13th International Conference on Nuclear Engineering (ICONE-13) (CD-ROM), 8 Pages, 2005/05
A hydrogen production system connected to the High-Temperature Engineering Test Reactor (HTTR) is being designed to be able to produce hydrogen using a nuclear heat of 10 MW supplied by the HTTR. The HTTR hydrogen production system is first connected to a nuclear reactor in the world, hence an mock-up model test is planned to carry out prior to the demonstration test of the HTTR hydrogen production system. In parallel to the mock-up model test, the following tests as an essential problem, a corrosion test of a reforming tube, a permeation test of hydrogen isotopes through a heat exchanger tube, an integrity test of a high-temperature isolation valve, and a performance test of a hydrogen permselective membrane are carried out to obtain detailed data for a safety review and development of analytical codes. This paper describes the present status of the component tests on the R&D of the HTTR hydrogen production system.
Sakaba, Nariaki; Matsuzawa, Takaharu*; Hirayama, Yoshiaki*; Nakagawa, Shigeaki; Nishihara, Tetsuo; Takeda, Tetsuaki
Proceedings of 2005 International Congress on Advances in Nuclear Power Plants (ICAPP '05) (CD-ROM), 8 Pages, 2005/05
The permeation of hydrogen isotopes through the Hastelloy XR high-temperature alloy adopted for the heat exchanger pipes of the intermediate heat exchanger in the HTTR (High Temperature Engineering Test Reactor) is one of the concerns in the hydrogen production system, which will be connected to the HTTR in the near future. An evaluation of the hydrogen permeation between the primary and secondary coolant through the Hastelloy XR was performed using the hydrogen concentration data observed during the initial 950C operation of the HTTR. The hydrogen permeability of the Hastelloy XR was estimated conservatively high as follows. The activation energy E and pre-exponential factor F of the permeability of hydrogen were E = 62 kJ/mol and F = 3.610 cm(NTP)/(cm s Pa), respectively, in the temperature range from 735K to 940K. The results implied that some oxidized film had been formed on the surface of the heat exchanger pipes of the intermediate heat exchanger.
Yoshida, Hajime; Kosaku, Yasuo*; Enoeda, Mikio; Abe, Tetsuya; Akiba, Masato
JAERI-Research 2005-003, 13 Pages, 2005/03
Hydrogen permeation fluxes of the reduced activation ferritic steel F82H were quantitatively measured by a newly proposed method, vacuum thermo-balance method, for a precise estimation of tritium leakage in a fusion reactor. We prepared sample capsules made of F82H, which enclosed hydrogen gas. The hydrogen in the capsules permeated through the capsule wall, and subsequently desorbed from the capsule surface during isothermal heating. The vacuum thermo-balance method allows simultaneous measurement of the hydrogen permeation flux by two independent methods, namely, the net weight reduction of the sample capsule and exhaust gas analysis. Thus the simultaneous measurements by two independent methods increase the reliability of the permeability measurement. The ratio of the hydrogen permeation fluxes obtained by the net weight reduction to that measured by the exhaust gas analysis was in the range from 1/4 to 1/1 in this experiment. It has been demonstrated that the vacuum thermo-balance method is effective for the measurement of hydrogen permeation rate of F82H.
Takeda, Tetsuaki; Iwatsuki, Jin*
Nuclear Technology, 146(1), p.83 - 95, 2004/04
Times Cited Count:12 Percentile:58.51(Nuclear Science & Technology)The objective of this study is to investigate the effect of the existence of hydrogen in a pipe outside on the amount of permeated deuterium through the pipe. It was found that the amount of permeated deuterium decreases with increasing the partial pressure of hydrogen in the pipe outside when the partial pressure of deuterium in the pipe is lower than 100 Pa and that of hydrogen in the pipe outside is higher than 10 kPa. The amount of permeated deuterium on counter permeation was predicted quantitatively by using an effectiveness factor for diffusivity of deuterium in metals and by taking into account the equilibrium state for hydrogen, deuterium and HD molecules on the metal surface. From the results obtained in this study, it is supposed that the amount of tritium transferred from the primary circuit of the HTTR to the hydrogen production system will be reduced by the existence of high-pressure hydrogen in the catalyst pipe of the steam reformer.
Ogawa, Hiroaki*; Kiuchi, Kiyoshi
JAERI-Research 2002-037, 48 Pages, 2002/12
The difference in hydrogen permeation among candidate cladding materials such as 25Cr-35Ni stainless steel, Nb liner and reference materials such as 18Cr-8Ni SS, and Zr of Zircaloy base metal were evaluated by low energy plasma permeation simulated to hydrogen excited by heavy neutron irradiation. RF excitation source was arranged for the experimental apparatus in cooperating with temperature and bias control. Comparing with the thermodynamic gas driven permeation (GDP) in the same hydrogen pressure, the hydrogen permeation rate by the plasma driven permeation (PDP) was markedly accelerated at low to medium temperature range. The temperature dependency showed a knick at around 530K due to hydrogen-defect interactions. Comparing with Zr, Nb showed the high hydrogen solubility without the degradation by hydrate formation that is required to a getter material. The difference in PDP among candidates was analyzed with a new dissolution model for hydrogen.
Shiozawa, Shusaku; Ogawa, Masuro; Inagaki, Yoshiyuki; Onuki, Kaoru; Takeda, Tetsuaki; Nishihara, Tetsuo; Hayashi, Koji; Kubo, Shinji; Inaba, Yoshitomo; Ohashi, Hirofumi
Proceedings of 17th KAIF/KNS Annual Conference, p.557 - 567, 2002/04
The research and development program on nuclear production of hydrogen was started on January in 1997 as a study consigned by Ministry of Education, Culture, Sports, Science and Technology. A hydrogen production system connected to the HTTR is being designed to be able to produce hydrogen of about 4000 m3/h by steam reforming of natural gas, using a nuclear heat of 10 MW supplied by the HTTR. In order to confirm controllability, safety and performance of key components in the HTTR hydrogen production system, the facility for an out-of-pile test was constructed on the scale of approximately 1/30 of the HTTR hydrogen production system. Essential tests are also carried out to obtain detailed data for safety review and development of analytical codes. Other basic studies on the hydrogen production technology of thermochemical water splitting called an iodine sulfur (IS) process, has been carried out for more effective and various uses of nuclear heat. This paper describes the present status and a future plan on the R&D of the HTTR hydrogen production systems in JAERI.
Nakamura, Hirofumi; Hayashi, Takumi; Nishi, Masataka; Arita, Makoto; Okuno, Kenji*
Fusion Engineering and Design, 55(4), p.513 - 520, 2001/09
Times Cited Count:9 Percentile:56.08(Nuclear Science & Technology)no abstracts in English
Nakamura, Hirofumi; Hayashi, Takumi; Kakuta, Toshiya*; Suzuki, Takumi; Nishi, Masataka
Journal of Nuclear Materials, 297(3), p.285 - 291, 2001/09
Times Cited Count:17 Percentile:74.85(Materials Science, Multidisciplinary)The isotope effect on the implantation-driven permeation of pure tritium (T) and deuterium (D) through nickel was investigated, respectively. The rate-determining processes of backward flow at the upstream surface and permeation at the down-stream surface were found to be as follows: recombination on up-stream surface and diffusion at down-stream side in a lower temperature region, whereas recombination on both surfaces in a higher temperature region for T and D, respectively. The diffusion coefficients of T and D derived by analyzing the obtained transient data of permeation in the lower temperature region were in good agreement with literature data of deuterium. The obtained activation energy of diffusion for T and D suggested the tendency of mass dependence. The surface recombination coefficients for both isotopes were also derived and showed in good agreement with literature data. As a result, the experimental results indicated the surface recombination could be attributed to the isotope effect of the permeation between T and D rather than the diffusion.
Nishihara, Tetsuo; Hada, Kazuhiko
Nihon Genshiryoku Gakkai-Shi, 41(5), p.571 - 578, 1999/05
Times Cited Count:5 Percentile:40.64(Nuclear Science & Technology)no abstracts in English
Shu, W.; Ohira, Shigeru; Nishi, Masataka
Trends in Physical Chemistry, 7, p.115 - 121, 1999/00
no abstracts in English
Nagasaki, Takanori; Ono, Hideo
J. Vac. Sci. Technol., A, 11(3), p.588 - 596, 1993/05
no abstracts in English
Katsuta, Hiroji; ;
Journal of Nuclear Materials, 115(2-3), p.206 - 210, 1983/00
Times Cited Count:25 Percentile:89.63(Materials Science, Multidisciplinary)no abstracts in English
Katsuta, Hiroji; R.B.McLellan*; Furukawa, Kazuo
Journal of Physics and Chemistry of Solids, 43(6), p.533 - 538, 1982/00
Times Cited Count:39 Percentile:88.17(Chemistry, Multidisciplinary)no abstracts in English
*; Katsuta, Hiroji; Furukawa, Kazuo; *
Journal of Nuclear Materials, 97(1-2), p.59 - 66, 1981/00
Times Cited Count:9 Percentile:73.24(Materials Science, Multidisciplinary)no abstracts in English
Katsuta, Hiroji; R.B.McLellan*; Furukawa, Kazuo
Proc.JIMIS-2,Hydrogen in Metals, p.113 - 116, 1980/00
no abstracts in English
Murakami, Yoshio;
Vacuum, 28(5), p.235 - 240, 1978/05
Times Cited Count:9no abstracts in English
Katsuta, Hiroji; Furukawa, Kazuo
Rev.Chim.Miner., 15(1), p.49 - 58, 1978/01
no abstracts in English